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Other Kinds of Water-Reducing Agents

Oil futures tumbled more than $5 a barrel on news that the Biden administration is considering releasing about 1 million barrels a day from the U.S. Strategic Petroleum Reserve (SPR) for several months to cool surging crude prices.

Brent crude futures were down $4.71, or 4.2 percent, at $108.58 a barrel by 0035 GMT. U.S. West Texas Intermediate futures fell $5.45, or 5 percent, to $102.74 a barrel.

At an earlier time, gasoline prices had already reached record levels because of the Russia-Ukraine conflict.

The prices of other commodities like the water reducer are also expected to be volatile.

Water reducing agents can be divided into ordinary water-reducing agents (also known as the plasticizing agent, whose water reducing rate is not less than 8%, represented by lignin sulfonic acid salts), high-efficient water-reducing agents (also called superplasticizer, whose water reducing rate is not less than 14%, including naphthalene, melamine, amino sulfonic acid salt, aliphatic, etc.) and high-performance water reducing agent (the water reducing rate is not less than 25%, represented by the polycarboxylate water-reducing agent).

Following is an introduction to five kinds of water-reducing agents.

 

Sulfamate High-efficient Water Reducing Agent:

The chemical name is aromatic amino sulfonate polymer. The production process is to use sodium aminobenzene sulfonic acid, and phenol as raw material, through addition, and the polycondensation reaction, a kind of polymerization of oita polymers will be produced. The water-reducing rate can reach 30%. The cost is relatively high, and it is easy to bleed. When used in combination with the naphthalene series high efficient water reducing agent, it can solve the problem of the naphthalene series high efficient water reducing agent and compatibility of cement. 

Sulfamate superplasticizer is a kind of monocyclic aromatic hydrocarbon type superplasticizer, mainly composed of p-sulfamate and monocyclic aromatic hydrocarbon derivatives. Phenol compounds will be combined with formaldehyde under acidic or alkaline conditions heat condensation.

The molecular structure of sulfamic acid superplasticizer is complex, and different monomers will have different molecular structures. 

 

Preparation Method:

The synthesis process is through the sulfamate superplasticizer and polyoxyeolefin compound polycondensation or with other compounds, such as lignosulfonate, catalytic graft to modify the sulfamate superplasticizer. The sulfamate series water reducing agent modified by polyoxy olefins polycondensation combines the advantages of polycarboxylate series and sulfamate series water reducing agent and has good working performance and early strength, but the raw material price is expensive and the production cost is high. 

The graft copolymerization of lignosulfonate and sulfamic acid superplasticizer can reduce the production cost and improve the segregation and bleeding of sulfamic acid superplasticizer.

 

Fatty Acids High-efficient Water-reducing Agents:

The chemical name is aliphatic hydroxyl sulfonate polymer. The raw materials are mainly acetone, formaldehyde, Na2SO3, Na2S2O5, catalyst, etc. It is brownish-red liquid. The water reduction rate can reach 20%, and it can be used for low-grade concrete and will make concrete stain. 

 

HSB aliphatic superplasticizer 

HSB (High Strence Bing) is a carbonyl pyroaldehyde synthesized by sulfonation of polymer.  Hydrophobic main chain for aliphatic hydrocarbons, it does not pollute the environment and does not damage human health. It has wide applicability to cement, obvious concrete enhancement effect, and small slump loss. Under conditions of low temperature, there is no sodium sulfate crystallization phenomenon. It is widely used in the preparation of pumping agents, delay setting, early strength, antifreeze, air, and other kinds of individual water reducing agents, and can also be used with naphthalene series water reducing agent, amino water reducing agent, polycarboxylate water reducing agent compound. 

 

Characteristics: 

1. High water reduction rate. Dosage is 1-2%, the water reduction rate is up to 15-25%. Under the condition of the same strength slump, adding HSB can save cement consumption by 25-30%.

2. Early strength and obvious enhancement effect. Concrete mixed with HSB can reach 60-70% of the design strength in three days, 100% in seven days, and 30-40% higher than blank concrete strength in 28 days. 

3. High plastic. Concrete slump loss is small, with almost no loss for 60 min and 10-20% for 90 min; 

4. Wide applicability to cement, workability, and good cohesion. Good compatibility with other kinds of admixtures; 

5. It can significantly improve the freeze-thaw resistance, seepage resistance, sulfate resistance of concrete, and comprehensively improve the other physical properties of concrete; 

6. It is especially suitable for the following concrete: flow plasticized concrete, natural curing, steam curing concrete, impermeable waterproof concrete, durable freeze-thaw resistant concrete, sulfate resistant Marine engineering concrete, and reinforced concrete, prestressed concrete; 

7. HSB is non-toxic, non-flammable, non-corrosive to steel bars, and has no sodium sulfate crystals in winter. 

 

Powder polycarboxylate 

It is a new type of high-performance water reducing agent, which has an excellent water reduction rate, fluidity, and permeability. Obviously, it can enhance the strength of cement mortar, but the production process is complex, and the general price is higher. 

 

Casein

It is a biopolymer made from milk precipitated with acid and dried in a cylinder. 

 

Suppliers of Concrete Additives

TRUNNANO is a reliable concrete additives supplier with over 12-year experience in nano-building energy conservation and nanotechnology development. If you are looking for high-quality concrete additives, please feel free to contact us and send an inquiry. (sales@cabr-concrete.com)

We accept payment via Credit Card, T/T, West Union, and Paypal. Trunnano will ship the goods to customers overseas through FedEx, DHL, by air, or by sea.


Southern Copper Corp (SCCO.N) recently said its Peruvian mine remained closed after a six-week standoff with protesters and blamed the Peruvian government for failing to intervene in the safety of its 1,300 workers and their families.  

The company said in a statement that a recent agreement to end protests at the Cuajone mine required the company to withdraw complaints against protest leaders because railways transporting minerals and supplies remained blocked. Production has been suspended since the end of February.  

Peru's Energy Ministry said in a separate statement that it had also reached an agreement with Southern Copper to start talks to find common ground with local communities.  

"If we shut down for a year, the government will stop receiving more than 3.1 billion soles ($830 million) in taxes and royalties, and 8,000 direct and indirect jobs will be lost. This is what we want to avoid, "Southern Copper added in the statement.

Peru has faced a wave of protests from indigenous communities, who accuse mining companies of not providing enough jobs and funding to poor local residents.  

Central bank officials said last week that protests against copper mines such as MMG's Las Bambas and Southern Copper's Cuajone were dragging down the economy.  

Peru is the world's second-largest copper producer and mining is an important source of tax revenue for the country. It is estimated that the supply and prices of the water reducer will be influenced by that.

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